REVIEW ARTICLE


C-C Forming Reactions with Palladium and Platinum: Lessons Learned in Our Group



Areej Hashim1, Abdullah Al-Hemyari1, Muna Bufaroosha1, Masataka Watanabe2, Krishna G. Dongol2, Thies Thiemann1, *
1 Department of Chemistry, College of Science, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates
2 Graduate School of Engineering and Institute of Materials and Chemical Engineering, Kyushu University, Fukuoka, Japan


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Creative Commons License
© 2018 Hashim et al.

open-access license: This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International Public License (CC-BY 4.0), a copy of which is available at: https://creativecommons.org/licenses/by/4.0/legalcode. This license permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

* Address correspondence to this author at the Department of Chemistry, College of Science, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates; Tel: +971-(0)56-692-5943; E-mail: thies@uaeu.ac.ae


Abstract

This short paper details our experiences with Pd- and Pt-catalyzed cross-coupling and cyclization reactions in investigations covering the years from 1997 until now. Pd-catalysed Suzuki-Miyaura-, Heck- and Sonogashira-type cross coupling reactions in conjunction with other transformations in one pot, especially with the Wittig reaction, are highlighted. This is followed by a description of a combination of Heck- and cyclization reactions. Finally, Pt-catalyzed diene-yne cyclization reactions are discussed.

Keywords: Suzuki-Miyaura reaction, Wittig olefination, Heck reaction, Sonogashira coupling, Diene-yne cyclization, Triene cyclization, Pd-catalysis, Pt-catalysis.